1) 5-nitro-1,10-phenanthroline
5-硝基-1,10-邻菲罗啉
2) 5-amino-1,10-phenanthroline
5-氨基-1,10-邻菲罗啉
1.
With recovered and regenerated 5% Pd/C as catalyst and hydrazine hydrate as reductant, 5-amino-1,10-phenanthroline was synthesized by reduction of 5-ntiro-1,10-phenanthroline which was synthesized from phenanthroline by nitration.
由1,10-邻菲罗啉经硝化制得5-硝基-1,10-邻菲罗啉,再经还原合成了5-氨基-1,10-邻菲罗啉。
3) 5-nitro-1,10-phenanthroline
5-硝基-1,10-菲绕啉
4) 1,10-phenanthroline
1,10-邻菲罗啉
1.
Hydrothermal Synthesis of Decavanadium Oxide Complex with 1,10-phenanthroline;
以1,10-邻菲罗啉为配体的钒氧酸盐配合物的水热合成
2.
Through the complexation of the two N atoms of 1,10-phenanthroline with the .
合成了配合物双(4-氨基苯甲酸)(1,10-邻菲罗啉)锌(Ⅱ),通过元素分析、红外光谱对其进行了表征。
3.
Three new solid complexes of rare earth (Ⅲ) with 2,4,5-Trichlorophenoxyacetic Acid and 1,10-Phenanthroline were synthesized in aqueous solution and the formula is RE(TCP)3·phen (RE=La,Nd,Er;TCP=2,4,5-Trichlorophenoxyacetate;phen=1,10-Phenanthroline).
在水相中合成三种新的稀土·三氯苯氧乙酸·邻菲罗啉固体配合物,其通式为RE(TCP)_3·phen(RE=La,Nd,Er;TCP=2,4,5-三氯苯氧乙酸;phen=1,10-邻菲罗啉)。
5) 5-acrylamido-1,10-phenanthroline
5-丙烯酰胺基-1,10-邻菲罗啉
1.
Using respectively 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone(PMBP,-diketone) and 5-acrylamido-1,10-phenanthroline as the first and second ligand,we synthesized the ternary chelates of yttrium-group rare earth metal ions Dy3+,Er3+,Tm3+ and Yb3+.
镧系金属(Ln)的钇组稀土离子Dy3+、Er3+、Tm3+、Yb3+分别与第一配体1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮(PMBP,β-二酮)、第二配体5-丙烯酰胺基-1,10-邻菲罗啉反应合成了钇组稀土离子-β-二酮-邻菲罗啉衍生物三元螯合物。
2.
Lanthanide metal cations,La3+,Pr3+,Nd3+,Eu3,Dy3+,Er3+,Tm3+ and Yb3+,reacted with the first ligand,1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone(PMBP)and the second ligand,5-acrylamido-1,10-phenanthroline(5-a-1,10-phen),respectively to form eight lanthanide metal cations——diketone-phenanthroline derivative ternary chelates with the uniform formula Ln(PMBP)3(5-a-1,10-phen).
以1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮(PMBP)为第一配体、5-丙烯酰胺基-1,10-邻菲罗啉(5-a-1,10-phen)为第二配体,分别与镧系元素(Ln)金属离子La3+、Pr3+、Nd3+、Eu3、Dy3+、Er3+、Tm3+、Yb3+合成了8个镧系金属-β二酮-邻菲罗啉衍生物三元螯合物Ln(PMBP)3(5-a-1,10-phen)。
6) 4,7-diphenyl-1,10-phenanthroline
4,7-二苯基-1,10-邻菲罗啉
1.
A novel supramolecular complex,[Cu(fum)(dpphen)_2]·CH_3OH·H_2O(fum=fumarate dianion,dpphen=4,7-diphenyl-1,10-phenanthroline),has been prepared from the reaction of bidentate ligand(dpphen),fumarate with CuCl_2,and were characterized by element analysis,IR,thermal analysis and X-ray diffraction technique.
利用螯合配体4,7-二苯基-1,10-邻菲罗啉与反丁烯二酸钠及铜盐反应合成了一种新型超分子配合物[Cu(fum)(dpphen)2]。
补充资料：硝基菲啶酮
分子式：
CAS号：
性质：有多种异构体。菲啶酮与浓硝酸发生硝化反应，得到83％2-硝基菲啶酮(熔点382～383℃)和14％4-硝基菲啶酮(熔点264～265℃)。其他异构体的熔点为：1-硝基菲啶酮，325～327℃；3-硝基菲啶酮，357～358℃；8-硝基菲啶酮，329℃；9-硝基菲啶酮，368℃；10-硝基菲啶酮，316～318℃。均为有机合成中间体。
CAS号：
性质：有多种异构体。菲啶酮与浓硝酸发生硝化反应，得到83％2-硝基菲啶酮(熔点382～383℃)和14％4-硝基菲啶酮(熔点264～265℃)。其他异构体的熔点为：1-硝基菲啶酮，325～327℃；3-硝基菲啶酮，357～358℃；8-硝基菲啶酮，329℃；9-硝基菲啶酮，368℃；10-硝基菲啶酮，316～318℃。均为有机合成中间体。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条